This study presents and discusses the results of soil radon monitoring at three different volcano sites and one reference site, from December 2007 to January 2009. This relates to the activity of the Popocatepetl Volcano and a radon survey and gamma-ray spectrometry in the area between Paso de Cortes and Tlamacas Mountain, and in the adjacent regions. The results are applied to the aspects of atmosphere electricity and lithosphere-atmosphere coupling in relation to the forecasting of volcano and earthquake activity. The monitoring of radon release reveals a decrease in radon concentration (down to total suppression) with approaching moderate volcanic eruptions. The behavior of the radon activity at the Tlamacas site is more apparent, compared to other observational sites. The average level of radon release observed at the Tlamacas site is much higher, with some characteristic variations. Both the radon survey and gamma-ray spectrometry indicate intensive diffusion radon emission localized in the area of Tlamacas Mountain. The average radon concentration in the area of Tlamacas is about 10-20-fold greater than the background volcano values. The new concept of lithosphere-atmosphere coupling is presented: intensive radon release in high elevated areas shortens and modifies the Earth-to-thunderclouds electric circuit, which provokes microdischarges into the air close to the ground, attracting lightning discharges. This concept attempts to explain in a new way the noise-like geomagnetic emissions registered before major earthquakes, and it promotes interest for the study of thunderstorm activity in seismo-active zones, as a promising instrument for earthquake forecasting.