Найдено научных статей и публикаций: 1, для научной тематики: Spin-correlated radical ion pairs
1.
O. M. Usov, V. M. Grigoryants, B. M. Tadjikov, Yu. N. Molin
- Radiation Physics and Chemistry , 1997
Amplitudes of quantum oscillations observed in the recombination fluorescence of the (diphenylsulfide-d10)+/(p-terphenyll-d14)− radical ion pairs in alkane solutions have been used to estimate a fraction of spin-correlated singlet pairs Θ in the radiation track. Θ values of 0.36 – 0.54 for the solve...
Amplitudes of quantum oscillations observed in the recombination fluorescence of the (diphenylsulfide-d10)+/(p-terphenyll-d14)− radical ion pairs in alkane solutions have been used to estimate a fraction of spin-correlated singlet pairs Θ in the radiation track. Θ values of 0.36 – 0.54 for the solvent series studied were found. Values for a fraction of singlet recombinations fs (0.52–0.66), calculated from Θ values, are in satisfactory agreement with those available from literature. It has been observed that Θ and fs values decrease with increasing solvent viscosity (from n-hexane to cis-decalin).
Radiat.Phys.Chem. 1997, V.49, No. 2, pp. 237-243
