Найдено научных статей и публикаций: 1, для научной тематики: X-ray analysis
1.
Natalia A.Sanina ,Sergey M.Aldoshin, Tatiana N.Rudneva ,Nina I.Golovina, Gennadyi V.Shilov ,Yurii M.Shulga ,Nicolai S.Ovanesyan , Vladimir N.Ikorskiy,ViktorI.Ovcharenko
- Journal of Molecular Structure , 2005
Bi-nuclear neutral paramagnetic nitrosyl iron complex[Fe2(C3H3N2S)2(NO)4]has been synthesized by the exchange reaction of
Na2Fe2(S2O3)2(NO)4*4H2O with imidazole-2-thiol. As it follows from X-ray analysis,complex (space group P2(1)/n, Z=2)has
centrosymmetric dimeric structure, with the iron atoms lin...
Bi-nuclear neutral paramagnetic nitrosyl iron complex[Fe2(C3H3N2S)2(NO)4]has been synthesized by the exchange reaction of
Na2Fe2(S2O3)2(NO)4*4H2O with imidazole-2-thiol. As it follows from X-ray analysis,complex (space group P2(1)/n, Z=2)has
centrosymmetric dimeric structure, with the iron atoms linked via structural fragment-m-N–C–S.Isomeric shift is 0.196(1)
mm/s and quadrupole resolution is 1.109(2)mm/s at T=293K. As follows from magnetic measurements,there are two
paramagnetic centers with spin 1/2 in molecules[Fe2(C3H3N2S)2(NO)4],which are connected by anti-ferromagnetic exchange (-34.6 cm-1).
Journal of Molecular Structure 752(2005)110–114
