Найдено научных статей и публикаций: 1, для научной тематики: Zn2+ probe
1.
P. Ashokkumar, V. T. Ramakrishnan, and P. Ramamurthy
- The Journal of Physical Chemistry A , 2011
Ratiometric sensors for the detection of metal ions
have gained increasing attention due to its self-calibration
tendency for the environmental effects. In this context, we have
synthesized and characterized a dual emitting ratiometric Zn2+
probe (1) having acridinedione as a fluorophore and N,N-bis...
Ratiometric sensors for the detection of metal ions
have gained increasing attention due to its self-calibration
tendency for the environmental effects. In this context, we have
synthesized and characterized a dual emitting ratiometric Zn2+
probe (1) having acridinedione as a fluorophore and N,N-bis(2-
pyridylmethyl)amine (BPA) as a receptor unit. Existence of two
different conformation of the molecule with photoinduced
electron transfer (PET) from amine moiety to the acridinedione
fluorophore leads to dual emission, namely locally excited
(425 nm) and anomalous charge transfer emission (560 nm) in aprotic solvents. In the presence of one equivalent of Zn2+, a
15-fold fluorescence enhancement in the locally excited state together with the quenching of charge transfer emission is observed.
The intensity changes at the two emission peaks allow a ratiometric detection of Zn2+ under PET signaling mechanism. The
utilization of PET process for the ratiometric fluorescence change will further signify the importance of PET mechanism in sensing
action. Addition of Zn2+ to 1 in acetonitrile/water mixtures shows a single emission peak with fluorescence enhancement.
J. Phys. Chem. A 2011, 115, 14292–14299