Найдено научных статей и публикаций: 5, для научной тематики: Hydrogen storage
1.
Muralidhar G. Chourashiya, Yong-Han Kim, Choong-Nyeon Park, Chan-Jin Park
- Journal of Alloys and Compounds , 2014
The present investigation evaluates the effect of milling the hydriding combustion synthesized (HCSed) MgNiC composite with NbF5 catalyst. X-ray analysis revealed that h-Mg-(1 0 1) peak positions of the ball-milled samples shifted by an amount that varied with the milling time. Morphologically, amon...
The present investigation evaluates the effect of milling the hydriding combustion synthesized (HCSed) MgNiC composite with NbF5 catalyst. X-ray analysis revealed that h-Mg-(1 0 1) peak positions of the ball-milled samples shifted by an amount that varied with the milling time. Morphologically, among the SPEX ball-milled samples the samples with the NbF5 catalyst showed slightly delayed refinement/agglomeration with milling time which was attributed to lubricating-behavior of NbF5 during milling. The final products from both (planetary and SPEX) ball mills showed insignificant agglomeration. A general trend of decreasing surface area with increasing milling time was observed. The HCSed sample manually mixed with catalyst showed the largest surface area of 23.78 m2/g. The presence of the catalyst and different interfaces, such as Mg–Nb, Mg–Ni and Mg–CNTs, in the samples played a crucial role in decreasing the thermal constraints for dehydrogenation. Analysis of hydrogenation kinetics revealed that the catalyst added samples requires activation and can be easily activated. By relating the hydrogenation kinetic data with the JMAK model, the value of the reaction order, n, was found to be close to 1 for all the samples, suggesting a possible diffusional phase transition. The lowest activation energy observed in synthesized sample for hydrogenation was 64.9 kJ/mol.
2.
• M.G. Chourashiya, C.N. Park, C.J. Park
- Functional Materials Letters , 2012
Superiority of the hydriding combustion (HC) technique over conventional metallurgical approach to the synthesis of cost-effective Mg based hydrides, which show promise as hydrogen storage materials, is well known. In the present research, we report further improvements in HC prepared Mg-based mater...
Superiority of the hydriding combustion (HC) technique over conventional metallurgical approach to the synthesis of cost-effective Mg based hydrides, which show promise as hydrogen storage materials, is well known. In the present research, we report further improvements in HC prepared Mg-based materials, achieved by optimizing the preparative parameters of HC and by catalytic addition. Mg90-Ni60-C40 composites prepared using optimized processing parameters were ball-milled with NbF5 (10 h) and characterized for their micro-structural and hydriding properties. The ball-milled/catalyzed powder showed decreased crystallinity with CNTs on its surfaces. Surface area of the ball-milled powder decreased to almost half of the as-HC powder, while TG analysis revealed a four-fold decrease in the desorption temperature of the milled powder compared to that of the as-HC prepared powder. Activated samples achieved the maximum absorption/desorption limits (5.3 wt.%) at as low as 100°C, underlining the possibility of the use of these materials in portable hydrogen storage devices.
3.
Muralidhar Chourashiya, Dong-Cheol Yang, Choong-Nyeon Park, Chan-Jin Park,
- nternational Journal of Hydrogen Energy , 2011
Magnesium may be the most promising solid-state hydrogen storage material owing to its high storage capacity (7.6 wt%) and highest volumetric density (2 times of liquid H2). On the other hand, suffers from its sluggish absorption/desorption characteristics. In the present study, the simple/cost-effe...
Magnesium may be the most promising solid-state hydrogen storage material owing to its high storage capacity (7.6 wt%) and highest volumetric density (2 times of liquid H2). On the other hand, suffers from its sluggish absorption/desorption characteristics. In the present study, the simple/cost-effective hydriding combustion synthesis (HCS) was used to prepare highly-active Mg-based-samples. The preparative parameters of HCS were varied, and its effects on the micro-structural and hydrogen storage properties were determined. The results and its analysis showed that the simple HCS process possesses a multifaceted dependence on a range of experimental factors and affect the final product. The estimated dependence enabled us to explain the combined effect of individual experimental factors on the prepared samples. The Mg–Ni–C sample prepared at 610 °C with 6%wt-nano-Ni and 4 wt%-multi-walled-CNTs as reactants, resulted in sample with a surface area as high as 19.01 m2/g and a desorption capacity of 5.77 wt%, highlighting the promising characteristics of HCS to prepare highly-active Mg-based-materials.
4.
Han-Sol Park, M.G. Chourashiya, Dong-Cheol Yang, Choong-Nyeon Park, Chan-Jin Park,
- Journal of Alloys and Compounds , 2011
This study examined the hydrogen storage and electrochemical characteristics of bcc type Ti0.32Cr0.43 − xV0.25Fex (x = 0–0.08) alloys and their ball-milled composites with AB5 type LmNi41Al0.25Mn0.3Co0.65 alloy. With increasing Fe content in the bcc alloy, the hydrogen storage capacity decreased and...
This study examined the hydrogen storage and electrochemical characteristics of bcc type Ti0.32Cr0.43 − xV0.25Fex (x = 0–0.08) alloys and their ball-milled composites with AB5 type LmNi41Al0.25Mn0.3Co0.65 alloy. With increasing Fe content in the bcc alloy, the hydrogen storage capacity decreased and the plateau pressure increased due to the decreased lattice volume. In addition, the plateau pressure of the bcc alloys decreased with decrease in its temperature. The discharge capacity of the composite alloys of bcc and AB5 alloy decreased with increasing Fe content in the bcc alloy at 25 °C, attributed to the increased plateau pressure. On the other hand, at low temperatures, the discharge capacity of the Fe-doped composite alloys was higher than that of the un-doped alloy due to the catalytic effect of Fe. In addition, with increasing discharge rate, the Fe-doped composite alloys with improved surface catalytic activity showed better discharge capacity.
5.
M.G. Chourashiya, D.C. Yang, S.Y. Kim, C.N. Park, C.J. Park,
- Materials Letters , 2011
This study employed a fast, simple and cost-effective hydriding combustion synthesis (HCS) to prepare nano/submicron Mg based alloys, which are the most promising solid state hydrogen storage materials owing to their high storage capacity (7.6 wt.%) and highest volumetric density. The microstructura...
This study employed a fast, simple and cost-effective hydriding combustion synthesis (HCS) to prepare nano/submicron Mg based alloys, which are the most promising solid state hydrogen storage materials owing to their high storage capacity (7.6 wt.%) and highest volumetric density. The microstructural and absorption/desorption kinetic properties of the prepared MgH2 samples were characterized and compared with commercially available MgH2 powders. The detailed BET analysis of the HCS prepared samples showed a higher surface area than that of commercial MgH2, which resulted in better absorption/desorption kinetics. The HCS-prepared MgH2 powder absorbed 6.2 wt.% H2 with a rate of 0.31 wt.%/min, whereas it desorbed at a rate of 0.98 wt.%/min. These results highlight the superiority of the HCS method to prepare MgH2 powders over conventional ingot-metallurgy.