Найдено научных статей и публикаций: 1, для научной тематики: N-acetyl-L-leucine
1.
G.A. Almanov, G.A. Bogdanchikov, O.M. Usov
- Radiation Physics and Chemistry , 1987
It has been found that the radical (CH3)2C̊CH2CH(NHCOCH3)CO2H transforms into (CH3)2CHCH2C̊(NHCOCH3)CO2H at temperatures of 293–315 K by the first-order reaction. The kinetic parameters determined for this reaction are k0 = 9.2 × 109s−1 and E‡ = 20.0 ±0.6 kcal/mole. The substitution of deuterium for...
It has been found that the radical (CH3)2C̊CH2CH(NHCOCH3)CO2H transforms into (CH3)2CHCH2C̊(NHCOCH3)CO2H at temperatures of 293–315 K by the first-order reaction. The kinetic parameters determined for this reaction are k0 = 9.2 × 109s−1 and E‡ = 20.0 ±0.6 kcal/mole. The substitution of deuterium for hydrogen in α-carbon does not affect the kinetic parameters which proves the absence of isotopic effects.
Radiat.Phys.Chem. 1987, V.29, No.1, 1987, pp.75-77
